They are composed of the metal rod immersed in its metal solution. The cell consists of both an indicator and reference electrode. These are mainly classified into three types of electrodes used in the potentiometry. New flow injection potentiometric graphite coated ion. The selectivity of the ise is determined by the composition of the membrane. These topics include junction potentials, reference electrodes, and the nernst equation.
As indicated by the name, ises possess a high degree of selectivity. Potentiometric analysis based on potential measurement of electrochemical cells without any appreciable current the use of electrodes to measure voltages from chemical reactions applications of potentiometric analysis components of a potentiometric cell 1. Platinum or au are used as metal indicator electrodes. Pdf an overview is given dealing with application of ionselective electrodes. Glass membrane electrode, indicator electrodes, potentiometry, metal electrodes, noble metal electrodes, gas sensing probe, oxide electrode, ion. Use of a high impedance voltmeter in important, because it ensures that current flow is. A,b, have been collected for ionophorebased ionselective electrodes ises for inorganic cations reported. Relationships between electrode potential and concentration are described by the nernst equation see text. Ion exchangers, ionophores, iron oxide nanoparticles, ion selective electrodes, polyions. In the most common forms of potentiometry, two different types of electrodes are used. Ion selective electrodes are mainly membranebased devices, consisting of permselective ion conducting materials, which separate the sample from the inside of the electrode fig. Glass, polymer, crystalline or glassgaspermeable membrane. Dec 04, 2012 two classes of indicator electrodes are used in potentiometry.
The past decade has seen the development and application of a diverse number of membrane electrodes. Consider a liquidbased ise, which has an the ion selective membrane is a. It is the measurement of the electrical potential difference between two electrodes, which, in contact with one or more electrolyte solutions, form an electrochemical cell. Potentiometric responses of ionselective electrodes doped. Mar 10, 2015 platinum or au are used as metal indicator electrodes. Determination of the sodium monofluorophosphate content of a toothpaste sample using a fluoride ionselective electrode. Other potentiometric electrode, such as ion selective electrodes, will exhibit a wider variation. Ionselective electrodes how they work respond selectively to only one ion key feature thin membrane, e. These electrodes respond to the ionic activity of the electrode. When an electrode used to measure ion a, also responds to ion x, the selectivity coefficient gives the relative response of the electrode to the two different species. Potentiometric ionselective electrodes request pdf. An alternative to wet liquid membrane electrodes is to use a polymeric membrane, which is composed of a polymer such as polyvinylchloride pvc, a plasticizer, and the ion carrier or exchanger. There is also a large group of ionselective electrodes ises sensitive to f.
Provides a basic introduction to potentiometry and the use of ion selective electrodes in chemical analysis. Just like a junction potential, an electric potential develops across the membrane due to the difference in concentration actually activity of the. As indicated by their name, ionselective electrodes possess a high degree of selectivity. Ionselective membrane electrodes an ionselective electrode consists of a thin membrane across which only the intended ion can migrate. Electrodes and potetiometry minnesota state university moorhead. Other ion selective electrodes respond to an analyte ion concentration difference in a way similar to that of the ph electrode.
Potentiometry and potentiometric titrations pdf free download. Ion selective membranes electrode is capable of binding only the intended ion. Comparative study of different potentiometric ionselective. This is the most widespread type of ion specific electrode.
Request pdf potentiometric ionselective electrodes the chapter emphasizes on potentiometric ionselective electrodes. The response of these electrodes is highly selective and they have replaced many liquid membrane electrodes. These electrodes are routinely used in clinical laboratories to determine various ion concentrations such as calcium in blood samples. Potentiometry methods involve measuring the potential between electrodes with no current flowing.
Electrodes of this type include potassium, calcium, chloride, fluoroborate, nitrate, perchlorate, potassium, and water hardness. Find out what metrohm has to offer for environmental analysis in air, soil, and water. There are mainly three types of the electrodes used in the potentiometry. This is the method in which the potential between two electrodes is measured while the electric current usually nearly zero between the electrodes is controlled. The main disadvantage is that they are not very selective. Ionselective electrodes, or ises, are probably the most important class of indicator electrodes. The author explains procedures step by step, and makes liberal use of worked examples. Sources of error in ionselective electrode potentiometry. Introduction to ion selective electrodes so far you have learned that during the technique of potentiometry, the potential, or voltage, of an electrochemical cell is measured. Ion selective electrodes we focus on ion selective electrodes that respond selectively to one type of ion. Scribd is the worlds largest social reading and publishing site. New, high quality ph electrodes will have a response in the range 95102 %, but older electrodes may be well under this range.
Ion exchange resins are based on special organic polymer membranes which contain a specific ion exchange substance resin. On the inside is a filling solution containing the ion of interest at a constant activity. Apr 17, 2018 glass membrane electrode, indicator electrodes, potentiometry, metal electrodes, noble metal electrodes, gas sensing probe, oxide electrode, ion selective electrode, first kind indicator electrode. Since the potential of the reference electrode is fixed, and the activity of the ion in the inner solution is constant, the measured cell potential reflects the potential of the ise, and can thus be. Provides a basic introduction to potentiometry and the use of ionselective electrodes in chemical analysis. These develop electric potential in response to a redox reaction on the metal surface. Ion selective electrode ise is a broad sub category of. Diureidocalix4arene, liquid membrane electrodes, benzoic acid, drink analysis. Computer analysis of data from potentiometric titrations using ion selective indicator electrodes.
Find upgrades, patches, documents, and language versions for your software here. Electrodes and potetiometry minnesota state university. In potentiometric measurements, the potential between two electrodes is measured using a high impedance voltmeter. Ionselective electrodes are potentiometric electrodes with a high degree of specificity for a single ion or class of ions. In potentiometry with ises, it is usually the emf of a cell of the. Often called ion selective electrodes ise or pion electrodes, because the data obtained from them are usually presented as pfunctions, ph, pca, pno 3 the general mechanism by which an ion selective potential develops in these devices depends on the nature of the membrane and is entirely different from the. Ideally the membrane allows the uptake of only one specific ion into it. Potentiometry is frequently used in one of two modes, namely a directmeasurement. The pvcbased membrane was coated on a graphite electrode with an effective area of 4. Wire lead air inlet to allow electrolyte to drain slowly through porous plug ag wire bent into a loop aqueous solution saturated with kci and agci. The development of potentiometric ionselective electrodes is a very. For example, ph, ion selective electrodes, blood gas analysis o 2, co 2, etc. Find out what metrohm has to offer for the monitoring of the water chemistry in thermal power plants, the wet chemical processing of solar cells and battery electrolytes, or electrochemical measurements of energy storage devices.
Potentiometry indicator electrodes solid state electrodes crystal electrodes example fluoride ion selective electrode laf 3 crystal is doped with euf 2 to provide vacancies holes of a fluoride ion site. Ion exchange resin membranes are based on organic ion exchangers and chelating agents. No electrode responds exclusively to one kind of ion. In your laboratory work you will use a fluoride ise. Ion selective electrodes, potentiometry, and potentiometric. With the advent of these sensors, potentiometry has entered a new era of usefulness ranging from fundamental studies of electrode mechanisms and the development of novel membrane materials to the more practical applications of pollution monitoring and clinical analysis. The membrane is usually nonporous, water insoluble, and mechanically. In recent years many texts have been published describing the use of ion selective electrodes for chemical analysis. Importance in environmental and medical applications. Since the potential of the reference electrode is constant, it is the potential developed. Serum protein monitoring and analysis with ion selective electrodes. Pdf ion selective electrodes in environmental analysis.
They are used in conjunction with a reference electrode and a high impedance voltmeter such as the ea165 phmv amp, to complete the measuring circuit in figure 2. Usage of specific resins allows preparation of selective electrodes for tens of different ions, both singleatom or multiatom. It is usually employed to find the concentration of a solute in solution. Potentiometry is one of the methods of electroanalytical chemistry. Potentiometry with ise is a comparatively recent development in the electrolyte analytical field.
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